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Author |
Owaga Ml, |
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Title |
The feeding ecology of wildbeest and zebra in Athi – Kaputei plains |
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Year |
1975 |
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Abbreviated Journal |
E Afr Wildl J |
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13 |
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375-384 |
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Notes |
from Professor Hans Klingels Equine Reference List |
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no |
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1445 |
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Author |
Pickett Bw, V.J. |
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Title |
Abnormalities of mating behaviour in domestic stallions |
Type |
Journal Article |
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Year |
1975 |
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Abbreviated Journal |
J Reprod Fert Suppl |
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Volume |
23 |
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Pages |
129-134 |
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from Professor Hans Klingels Equine Reference List |
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no |
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1470 |
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Author |
Rossdale Pd, |
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Title |
Das Pferd, Fortpflanzung und Entwicklung |
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Year |
1975 |
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Abbreviated Journal |
Karger 1975 |
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Notes |
from Professor Hans Klingels Equine Reference List |
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no |
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Serial |
1519 |
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Author |
Ruckebusch Y, |
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Title |
The hypnogram as an index of adaptation of farm animals to changes in their environment |
Type |
Journal Article |
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Year |
1975 |
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Abbreviated Journal |
App Anim Ethol |
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Volume |
2 |
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3-18 |
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Notes |
from Professor Hans Klingels Equine Reference List |
Approved |
no |
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Call Number |
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Serial |
1531 |
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Author |
Short Rv, |
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Title |
The evolution of the horse |
Type |
Journal Article |
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Year |
1975 |
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Abbreviated Journal |
J Reprod Fert Suppl |
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Volume |
23 |
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1-6 |
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Notes |
from Professor Hans Klingels Equine Reference List |
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no |
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Serial |
1589 |
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Author |
Smuts Gl, |
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Title |
Home range sizes for Burchell's Zebra, Equus burchelli antiquorum from the Krüger National Park |
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Journal Article |
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Year |
1975 |
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Koedoe |
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18 |
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Pages |
139-146 |
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Notes |
from Professor Hans Klingels Equine Reference List |
Approved |
no |
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Call Number |
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Serial |
1612 |
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Author |
Smuts Gl, |
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Title |
Pre – and postnatal growth phenomena of Burchell's Zebra, Equus Burchelli Antiquorum |
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Journal Article |
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Year |
1975 |
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Abbreviated Journal |
Koedoe |
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Volume |
18 |
Issue |
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Pages |
69-102 |
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Notes |
from Professor Hans Klingels Equine Reference List |
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no |
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Serial |
1613 |
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Author |
Welsh Da, |
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Title |
Population, behavioural, and grazing ecology of the Sable Island, Nova Scotia. |
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Manuscript |
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Year |
1975 |
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Ph.D. thesis |
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Dalhousie University |
Place of Publication |
Halifax |
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Notes |
from Professor Hans Klingels Equine Reference List |
Approved |
no |
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Call Number |
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Serial |
1702 |
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Author |
Western D, |
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Title |
Water availability and its influence on the structure and dynamics of a savannah large mammal community |
Type |
Journal Article |
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Year |
1975 |
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Abbreviated Journal |
E Afr Wildl J 1 |
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Volume |
3 |
Issue |
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Pages |
265-288 |
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Notes |
from Professor Hans Klingels Equine Reference List |
Approved |
no |
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Serial |
1704 |
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Author |
Czerlinski, G.H.; Wagner, M.; Erickson, J.O.; Theorell, H. |
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Title |
Chemical relaxation studies on the system liver alcohol dehydrogenase, NADH and imidazole |
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Journal Article |
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Year |
1975 |
Publication |
Acta Chemica Scandinavica. Series B: Organic Chemistry and Biochemistry |
Abbreviated Journal |
Acta Chem Scand B |
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Volume |
29 |
Issue |
8 |
Pages |
797-810 |
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Keywords |
Alcohol Oxidoreductases/*metabolism; Animals; Computers; Hydrogen-Ion Concentration; Imidazoles/*metabolism; Kinetics; Liver/enzymology/*metabolism; Mathematics; Models, Chemical; NAD/*metabolism; Time Factors |
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Abstract |
Several years ago, Theorell and Czerlinski conducted experiments on the system of horse liver alcohol dehydrogenase, reduced nicotinamide adenine dinucleotide and imidazole, using the first version of the temperature jump apparatus with detection of changes in fluorescence. These early experiments were repeated with improved instrumentation and confirmed the early experiments in general terms. However, the improved detection system allowed to measure a slight concentration dependence of the relaxation time of around 3 ms. Furthermore, the chemical relaxation time was smaller than the one determined earlier (by factor 2). The data were evaluated much more rigorously than before, allowing an appropriate interpretation of the results. The observed relaxation time is largely due to rate constants in an interconversion of ternary complexes, which are faster than three (of the four) dissociation rate constants, determined previously by Theorell and McKinley-McKee.1,2 This fact contributed to earlier difficulties of finding any concentration dependence. However, the binding of imidazole to the binary enzyme-coenzyme complex can be made to couple kinetically into the interconversion rate of the two ternary complexes. The observed signal derives largely from the ternary complex(es). A substantial fluorescence signal change is associated with the observed relaxation process, suggesting a relocation of the imidazole in reference to the nicotinamide moiety of the bound coenzyme. Nine models are considered with two types of coupling of pre-equilibria (none-all). Quantitative evaluations favor the model with two ternary complexes connected by an interconversion outside the four-step (bimolecular) cycle. The ternary complex outside the cycle has much higher fluorescence yield than the one inside. The interconversion equilibrium is near unity for imidazole. If it would be shifted very much to the side of the “dead-end” complex (as in isobutyramide?!), stimulating action could not take place. |
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English |
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0302-4369 |
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PMID:882 |
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refbase @ user @ |
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3887 |
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